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Stress quantification can be observed during single fiber pull-out test in a polymer matrix composite with stress sensing molecules. 

Abstract Understanding the stress distribution within fiber‐reinforced polymers (FRPs) is critical to extending their operational lifespan. The integration of mechanoresponsive molecular force probes, referred to as mechanophores, presents a potential solution by enabling direct monitoring of stress concentrations. In this study, spiropyran (SP) mechanophores (MPs) are embedded within a polydimethylsiloxane (PDMS) matrix to visualize stress localization during loading within a single fiber‐reinforced framework. The SP mechanophore undergoes a transition from a non‐fluorescent state to an active state (merocyanine) through isomerization in response to mechanical forces. Using a single fiber mounted axially within the matrix, the fundamental failure modes observed in conventional fiber‐reinforced composites are replicated. Samples are strained under uniaxial tensile loading along the fiber direction and the localization of stresses is observed via MP activation. Stresses are concentrated in the matrix near the fiber region that gradually decreases away from the fiber surface. Confocal microscopy is used to visualize mechanophore activation and quantitatively assess fluorescence intensity. Finite element modeling is used to develop a calibration to quantify the stresses based on the observed fluorescence intensity. These outcomes underscore the viability of employing these mechanoresponsive molecules as a potential means to visualize real‐time stress distribution, thereby facilitating the design of high‐performance composites. 

Abstract Force‐responsive molecules that produce fluorescent moieties under stress provide a means for stress‐sensing and material damage assessment. In this work, we report a mechanophore based on Diels‐Alder adductTAD‐Anof 4,4′‐(4,4′‐diphenylmethylene)‐bis‐(1,2,4‐triazoline‐3,5‐dione) and initiator‐substituted anthracene that can undergo retro‐Diels‐Alder (rDA) reaction by pulsed ultrasonication and compressive activation in bulk materials. The influence of having C−N versus C−C bonds at the sites of bond scission is elucidated by comparing the relative mechanical strength ofTAD‐Anto another Diels‐Alder adductMAL‐Anobtained from maleimide and anthracene. The susceptibility to undergo rDa reaction correlates well with bond energy, such that C−N bond containingTAD‐Andegrades faster C−C bond containingMAL‐Anbecause C−N bond is weaker than C−C bond. Specifically, the results from polymer degradation kinetics under pulsed ultrasonication shows that polymer containingTAD‐Anhas a rate constant of 1.59×10⁻⁵ min⁻¹, whileMAL‐An(C−C bond) has a rate constant of 1.40×10⁻⁵ min⁻¹. Incorporation ofTAD‐Anin a crosslinked polymer network demonstrates the feasibility to utilizeTAD‐Anas an alternative force‐responsive probe to visualize mechanical damage where fluorescence can be “turned‐on” due to force‐accelerated retro‐Diels‐Alder reaction. 

In this study, a sulfonation approach using chlorosulfonic acid (CSA) to prepare cellulose sulfate nanofibers (CSNFs) from raw jute fibers is demonstrated. Both elemental sulfur content and zeta potential in the CSNFs are found to increase with increasing CSA content used. However, the corresponding crystallinity in the CSNFs decreases with the increasing amount of CSA used due to degradation of cellulose chains under harsh acidic conditions. The ammonium adsorption results from the CSNFs with varying degrees of sulfonation were analyzed using the Langmuir isotherm model, and the analysis showed a very high maximum ammonium adsorption capacity (41.1 mg/g) under neutral pH, comparable to the best value from a synthetic hydrogel in the literature. The high ammonium adsorption capacity of the CSNFs was found to be maintained in a broad acidic range (pH = 2.5 to 6.5). 

A bstract We construct the four-derivative supersymmetric extension of (1, 0), 6 D supergravity coupled to Yang-Mills and hypermultiplets. The hypermultiplet scalars are taken to parametrize the quaternionic projective space Hp ( n ) = Sp( n , 1)/Sp( n ) × Sp(1) R . The hyperscalar kinetic term is not deformed, and the quaternionic Kähler structure and symmetries of Hp ( n ) are preserved. The result is a three parameter Lagrangian supersymmetric up to first order in these parameters. Considering the case of Hp (1) we compare our result with that obtained from the compactification of 10 D heterotic supergravity on four-torus, consistently truncated to N = (1, 0), in which the hyperscalars parametrize SO(1, 4)/SO(4). We find that depending on how the Sp(1) is embedded in the SO(4), the results agree for a specific value of the parameter that governs the higher derivative hypermultiplet couplings. 

In the context of continued spread of coronavirus disease 2019 (COVID-19) caused by SARS-CoV-2 and the emergence of new variants, the demand for rapid, accurate, and frequent detection is increasing. Moreover, the new predominant strain, Omicron variant, manifests more similar clinical features to those of other common respiratory infections. The concurrent detection of multiple potential pathogens helps distinguish SARS-CoV-2 infection from other diseases with overlapping symptoms, which is significant for providing tailored treatment to patients and containing the outbreak. Here, we report a lab-on-a-chip biosensing platform for SARS-CoV-2 detection based on the subwavelength grating micro-ring resonator. The sensing surface is functionalized by specific antibody against SARS-CoV-2 spike protein, which could produce redshifts of resonant peaks by antigen–antibody combination, thus achieving quantitative detection. Additionally, the sensor chip is integrated with a microfluidic chip featuring an anti-backflow Y-shaped structure that enables the concurrent detection of two analytes. In this study, we realized the detection and differentiation of COVID-19 and influenza A H1N1. Experimental results indicate that the limit of detection of our device reaches 100 fg/ml (1.31 fM) within 15 min detecting time, and cross-reactivity tests manifest the specificity of the optical diagnostic assay. Furthermore, the integrated packaging and streamlined workflow facilitate its use for clinical applications. Thus, the biosensing platform presents a promising approach for attaining highly sensitive, selective, multiplexed, and quantitative point-of-care diagnosis and distinction between COVID-19 and influenza. 

Stress concentrations in polymer matrix composites occur due to non-uniform loadings which develop near the interface between the matrix and reinforcement in a stressed composite. Methods to better understand the evolution of this stress concentration are required for the development of advanced composites. Mechanophores, which are stress responsive molecules, can be embedded into the polymer matrix and used to quantify the local stresses in a loaded composite. In this work, single particle model composites were fabricated by combining functionalized glass particles embedded into a silicone/mechanophore matrix. Confocal microscopy was then used to measure the mechanophore activationin situduring mechanical loading. The fluorescence intensity was correlated to maximum principal stress values obtained from a finite element analysis (FEA) model of the system utilizing an Ogden hyperelastic model to represent the elastomer. By calibrating stress to fluorescence intensity spatially, quantitative stress measurements can be obtained directly from fluorescent images. To validate this technique, calibrated stress values for a two-particle composite system were compared to a FEA model and good agreement was found. Further experiments were performed on silicone matrix composites containing short cylindrical particles oriented with their major axis parallel or perpendicular to the stretching direction. To demonstrate the versatility of the single particle intensity/stress calibration approach, maximum principal stress values were mapped on the fluorescence images of the cylindrical experiments. This technique has potential to quantify stress concentrations quickly and accurately in new composite designs without the use of FEA models or differential image correlation. 

A bstract There exist two four-derivative extensions of N = (1, 0) supergravity in six dimensions. A particular combination of them is known to dualize to the analog of the Bergshoeff-de Roo (BdR) action in 10 D . Here we first show that the two extensions are not related to each other by any field redefinitions. Next, we dualize them separately thereby obtaining a two parameter dual theory. This is done directly at the level of the action, thus avoiding the laborious method of integrating equations of motion of the dualized theory into an action. To explore whether a similar phenomenon exists in 10 D , we study the dualization of the BdR action in 10 D in detail. We find an obstacle in the separation of the result into a sum of two independent invariants because of the presence of terms which do not lift from 6 D to 10 D . We also compare the dual of the BdR action with an existing result obtained in superspace. We find that the bosonic actions agree modulo field redefinitions. 

A bstract Higher derivative couplings of hypermultiplets to 6 D, N = (1 , 0) supergravity are obtained from dimensional reduction of 10D heterotic supergravity that includes order α ′ higher derivative corrections. Reduction on T 4 is followed by a consistent truncation. In the resulting action the hyperscalar fields parametrize the coset SO(4 , 4) / (SO(4) × SO(4)). While the SO(4 , 4) symmetry is ensured by Sen’s construction based on string field theory, its emergence at the field theory level is a nontrivial phenomenon. A number of field redefinitions in the hypermultiplet sector are required to remove several terms that break the SO(4) × SO(4) down to its SO(4) diagonal subgroup in the action and the supersymmetry transformation rules. Working with the Lorentz Chern-Simons term modified 3-form field strength, where the spin connection has the 3-form field strength as torsion, is shown to simplify considerably the dimensional reduction.